徐征

发布人：苏丽

时间： 2013-01-17

点击： 0

个人简历

徐征博士副研究员

女，汉族，1978年生，杭州师范大学有机硅化学及材料技术教育部重点实验室副研究员。主要研究方向功能有机硅高分子材料的制备过程中的结构和性能控制机制，新型有机硅化合物反应机理、功能有机硅聚合物的分子模拟与设计、分子间相互作用与材料力学性能之间的关系等。目前，在具有较高影响力的国际期刊上发表30余篇论文，承担并主持国家自然科学基金青年基金1项目、浙江省自然科学基金2项及杭州市科技发展计划项目1项。

学习工作经历

1996.9-2000.7 福建省国立华侨大学　化学工程专业　学士

2001.9-2004.3 浙江大学　物理化学专业　硕士

2004.3-2007.3 浙江大学　化学生物学（物理化学）　博士

2007.5-2009.9　杭州师范大学有机硅实验室　助理研究员

2009.9-至今　杭州师范大学有机硅实验室　副研究员

ü 主持项目

1．关于弱氢键在硅橡胶补强中的地位和作用，浙江省自然科学基金， Y4090470，8.5万，2010年1月至2011年12月

2. 结合红外和理论计算研究白炭黑与聚硅氧烷间的相互作用，国家自然科学基金青年基金，20903032，20万，2010年1月至2012年12月

3. 过渡金属催化的芳烃/卤代芳烃硅烷基化反应研究，浙江省自然科学基金， LY17B030005, 9.0万，2017年1月至2019年12月

4. 高效多功能有机硅类抗菌防霉剂的研制及应用,杭州市科技发展计划项目，20170533B08，10.0万，2016年9月至2019年9月

ü 近年来代表性科研成果

1. Mu, Q.-C.; Nie, Y.-X.; Bai, X.-F.; Chen, J;* Yang, L.; Xu, Z.;* Li, L.; Xia, C.-G.; Xu, L.-W.;* Tertiary Amine-directed and Involved Carbonylative Cyclizations through Pd/Cu-cocatalyzed Multiple C-X (X=H or N) Bond Cleavage, Chem. Sci. 2019, DOI: 10.1039/C9SC03081F

2. Su, Y.-L.; Wang, X.-B.; Sun, F.-N.; Chen, Q.-Q.; Cao, J.;* Xu, Z.;* Xu, L.-W.* Enantioselective Cross-Exchange between C−I and C−C σ‑Bonds. Angew. Chem. Int. Ed. 2019, 58, 6747.

3. Long, P.-W.; Bai, X.-F.; Ye, F.; Li, L.; Xu, Z.; * Yang, K.-F.; Cui, Y.-M.; Zheng, Z.-J.; Xu, L.-W.* Construction of Six-Membered Silacyclic Skeletons via Platinum-Catalyzed Tandem Hydrosilylation/Cyclization with Dihydrosilanes, Adv. Synth. Catal. 2018, 360, 2825.

4. Long, P.-W.; Xu, J.-X.; Bai, X.-F.; Xu, Z.;* Zheng, Z.-J.; Yang, K.-F.; Li, L.; Xu, L.-W. * Palladium-catalyzed tandem allylic substitution/cyclization and cascade hydrosilylated reduction: the influence of reaction parameters and hydrosilanes on the stereoselectivity, RSC Adv. 2018, 8, 22944.

5. Xu, Z.,* Xu, J.-Z., Zhang, J., Zheng, Z.-J., Cao, J., Cui, Y.-M., and Xu, L.-W.* Mechanistic Insights into Palladium-Catalyzed Silylation of Aryl Iodides with Hydrosilanes through a DFT Study. Chem.- Asian J. 2017, 12, 1749-1757.

6. Huang, J.-B., Bai, X.-F., Li, L., Zheng, Z.-J., Xu, Z.,* Cui, Y.-M., Cao, J., and Xu, L.-W.* Transition-Metal-Free Oxidative C(sp(2))-H Hydroxylation of Terpyridines: A HOMO-Raising Strategy for the Construction of a New Super-Stable Terpyridine Chromophores. Chem.- Eur. J. 2017, 23, 4055–4059.

7. Zhang, J., Xu, J.-Z., Zheng, Z.-J, Xu, Z.,* Cui, Y.-M., Cao, J., and Xu, L.-W.* Palladium-Catalyzed Desymmetrization of Silacyclobutanes with Alkynes to Silicon-Stereogenic Silanes: A Density Functional Theory Study, Chem. Asian J. 2016, 11, 2867 - 2875.

8. Xu, Z., Huang, W.-S., Zhang, J., and Xu, L.-W.* Recent Advances in Transition-Metal-Catalyzed Silylations of Arenes with Hydrosilanes: C-X Bond Cleavage or C-H Bond Activation Synchronized with Si-H Bond Activation. Synthesis 2015, 47, 3645-3668.

9. Xu, Z., and Xu, L.-W.* Silylations of Arenes with Hydrosilanes: From Transition-Metal-Catalyzed. Chemsuschem 2015, 8, 2176-2179.

10. Xu, Z., and Xu, L.-W.* Development of Ar-BINMOL-Derived Atropisomeric Ligands with Matched Axial and sp(3) Central Chirality for Catalytic Asymmetric Transformations. Chem. Record 2015, 15, 925-948.

11. Huang, N., Xu, J., Zhang, H., and Xu, Z.* The Origin of the Decreasing Basicity from Monofunctional Alkoxysilane to Tetrafunctional Alkoxysilane: A Combined IR and Theoretical Study. J. Mol. Struct. 2015, 1089, 216-221.

12. Xu, Z., Jin, J., Zhang, H., Li, Z., Jiang, J., Lai, G., and Kira, M. Insertion of Silylenes into Si-H and Si-Cl Bonds. Comparison of Mechanism and Substituent Effects. Organometallics 2011, 30, 3311-3317.

13. Xu, Z., Jin, J., Li, Z., Qiu, H., Jiang, J., Lai, G., and Kira, M. Remarkable Substituent Effects on the Activation Energy of Silylene Insertion into Silicon-Chlorine Bonds. Chem. - Eur. J. 2009, 15, 8605-8612.

14. Lai, G., Xu, Z., Li, Z., Jiang, J., Kira, M., and Qiu, H. Stereoelectronic Substituent Effects on Silylene Insertion into the Si−Cl Bond. Organometallics 2009, 28, 3591-3593.

15. Xu, Z., Li, H., and Wang, C. Can a blue shift of the C-H stretching modes of inactivated C groups be an indicator of weak C-H…O hydrogen bonds? Chemphyschem 2006, 7, 2460-2463.

16. Xu, Z., Jin, J., Li, Z., Qiu, H., Jiang, J., Lai, G., and Kira, M. Remarkable Substituent Effects on the Activation Energy of Silylene Insertion into Silicon-Chlorine Bonds. Chem. - Eur. J. 2009, 15, 8605-8612.

17. Xu, Z., Jin, J., Zhang, H., Li, Z., Jiang, J., Lai, G., and Kira, M. Insertion of Silylenes into Si-H and Si-Cl Bonds. Comparison of Mechanism and Substituent Effects. Organometallics 2011, 30, 3311-3317.

联系方式：

邮箱：zhengxu@hznu.edu.cn

电话：0571-28868720