厉嘉云

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【个人简介】:厉嘉云,女,博士,高级实验师,浙江杭州人。现主要从事咪唑类离子液体、N-杂环卡宾金属配合物及其在清洁催化转化中的应用研究、硅氢加成催化剂方面研究,相关研究工作已申请发明专利二十余项,并在New Journal of chemistryJournal of Organometallic ChemistryJournal of Molecular Catalysis A: ChemicalCatalysis CommunicationsTetrahedron LettersAppl. Organometal. Chem.和化学学报、有机化学等国内外学术期刊上发表SCI论文四十余篇,主持多项国家及省部级项目。

【电子邮件】: jiayun1980@hznu.edu.cn
【主要学历】
1998.09—2002.07 学士(工学),浙江工业大学
2002.09—2005.07 硕士(工学),浙江工业大学
2007.09—20011.07 博士(工学),浙江工业大学
【主要工作经历】
2005.7-2011.09  杭州师范大学有机硅实验室,实验师
2011.09-至今  杭州师范大学有机硅实验室,高级实验师
【主要研究方向】
l  有机合成
l 绿色催化
l 硅氢加成
【主要科研项目】
1.用于烷(氧)基氢硅烷硅氢加成反应的功能化离子液体及其固载化研究浙江省自然科学基金,8万元,2010.1-2012.12,项目负责人。
2.功能化离子液体在硅烷偶联剂合成反应中的应用研究杭州市属高校重点实验室科技创新项目,10万元,2010.1-2012.12,项目负责人。
3.基于烷(氧)基硅烷硅氢加成反应构建官能化咪唑盐-过渡金属配合物催化体系的研究国家青年科学基金2013.1-2015.12,项目负责人。
【代表性论著】
1.       Effect of carboxyl-functionalized imidazolium salts on the rhodium catalyzed hydrosilylation of alkene, J. Organomet. Chem. 2013, 727, 28-36.
2.      Synthesis of rhodium N-heterocyclic carbene complexes and their catalytic activity in the hydrosilylation of alkenes in ionic liquid medium, J. Organomet. Chem. 2011, 696, 2116-2121.
3.      Effect of triarylphosphane ligands on the rhodium-catalyzed hydrosilylation of alkene, Appl. Organometal. Chem. 2014, 28, 120-126.
4.      Study on the anti-sulfur-poisoning characteristics of platinum-acetylide-phosphine complexes as catalysts for hydrosilylation reactions, Appl. Organometal. Chem. 2014, 28, 454-460.
5.      Asymmetric Zinc-Catalyzed Hydrosilylation of Ketones and the Effect of Carboxylate on the Enantioselectivity Chirality 2013, 25, 275-280.
6.      Hydrosilylation of alkenes catalyzed by rhodium with polyethylene glycol-based ionic liquids as ligands, J. Organomet. Chem. 2014, 765, 59-63.
7.      Use of functionalized PEG with 4-aminobenzoic acid stabilized platinum nanoparticles as an efficient catalyst for the hydrosilylation of alkenes, J. Colloid. Interf. Sci. 2013, 394, 428-433.
8.      Functional Polyethylene Glycol with Carboxyl-supported Platinum as an Efficient Catalysis System for the Hydrosilylation of Alkenes, Chinese J. Chem. Eng. 2012, 20(2), 246-253.
9.      Functionalized Silica Immobilized Platinum Catalyst and Its Application in the Catalytic Hydrosilylation of Alkenes, Curr. Catal. 2012, 1, 180-185.
10. Synthesis of platinum acetylide complexes and their application in curing silicone rubber by hydrosilylation, Appl. Organometal. Chem. 2012, 26, 461-466.
11. Highly efficient and convenient asymmetric hydrosilylation of ketones catalyzed with zinc Schiff base complexes, Tetrahedron, 2012, 68, 1371-1375.
12. Hydrosilylation reactions catalyzed by rhodium complexes with phosphine ligands functionalized with imidazolium salts, J. Organomet. Chem. 2011, 696, 263-268.
14. Rh(PPh3)3Cl/Tetrakis(Dialkylamino)Phosphonium Salts as Thermoregulated and Recyclable Catalytic System for Hydrosilylation Reaction, Phosphorus, Sulfur Silicon Relat. Elem. 2011, 186, 2116-2121.
15. Phosphines with 2-imidazolium ligands enhance the catalytic activity and selectivity of rhodium complexes for hydrosilylation reactions, J. Organomet. Chem. 2010, 695, 431-436.
16. Hydrosilylation Catalyzed with Rh(PPh3)3Cl/Ionic-Liquid-Functionalized SiO2,Phosphorus, Sulfur Silicon Relat. Elem. 2010, 185, 484-490.
17. Synthesis of Polyethyleneglycol (PEG) Functionalised Ionic Liquids and the Application on HydrosilylationCatal. Commun. 2008, 10, 248-250.
18. Rh(PPh3)3Cl/Ionic Liquid (Molten Salt) as a Thermoregulated and Recyclable Catalytic System for Hydrosilylation, J. Mol. Catal. A: Chem. 2007, 278, 97-101.
19. Ionic Liquid (Molten Salt): Thermoregulated Catalyst Support for Catalytic Hydrosilylation Process, Catal. Commun. 2008, 9, 2236-2238.
20. Rh(PPh3)3Cl/有机融盐催化烯烃硅氢加成反应, 化学学报 2008, 66, 1009-1014.
21. Effect of Aminoaromatic Acids as Additives on the Activity and Selectivity of the Platinum-catalyzed Hydrosilylation of Alkenes, Chin. J. Chem. Engin. 2009, 17, 1038-1042.
22. 过渡金属钌、铑配合物在室温离子液体中催化硅氢加成反应的研究, 化学学报 2007, 65, 715-721.
23. Impact of Substituents Attached to N-Heterocyclic Carbenes on the Catalytic Activity of Copper Complexes in the Reduction of Carbonyl Compounds with Triethoxysilane, 中国化学2009, 27, 2121-2124.