曹建

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【个人简介】：曹建，浙江大学博士，助理研究员。目前承担国家自然科学基金一项以及浙江省自然科学基金一项。现在主要从事氮，氧，硅等杂原子取代的炔烃的有机合成反应研究。

【电话】：13685776931

【电子邮件】： caojian@hznu.edu.cn

【主要学历】

2001.09-2005.07 浙江大学化学系，本科生，获理学学士

2005.09-2010.07 浙江大学化学系，研究生，获理学博士

【主要研究方向】

1. 新型串联反应研究

2. 有机硅化合物在有机合成中的应用

【主要科研项目及角色】

目前主持国家自然科学基金一项以及浙江省自然科学基金一项

【代表性论著】

1. Synthesis of α,β-Unsaturated Amides and Iminocoumarins from N,N-Disulfonyl Ynamides with Aldehydes via the Ketenimine Intermediate.

Lian Yu, Jian Cao*

Org. Biomol. Chem. 2014, 12, 3986.

2. Synthesis of N-Sulfonylamidines by Catalyst-Free Hydroamination of Ynamides and Amines.

Yulong Kong, Lian Yu, Yuming Cui, Jian Cao*

Synthesis 2014, 46, 183.

3. Synthesis of 3-Alkyl- or 3-Allenyl-2-amidobenzofurans via Electrophilic Cyclization of o-Anisole-substituted Ynamides with Carbocations.

Yulong Kong, Kezhi Jiang, Jian Cao,* Lingzi Fu, Lian Yu, Guoqiao Lai, Yuming Cui, Ziqiang Hu, Guanhai Wang

Org. Lett. 2013, 15, 422.

4. Electrophilic Cyclization of o-Anisole- and o-Thioanisole-Substituted Ynamides: Synthesis of 2-Amidobenzofurans and 2-Amidobenzothiophenes.

Yulong Kong, Lian Yu, Lingzi Fu, Jian Cao,* Guoqiao Lai, Yuming Cui, Ziqiang Hu, Guanhai Wang

Synthesis 2013, 45, 1975.

5. Synthesis of Allenamides by Pd-catalyzed Coupling of 3-Alkoxycarbonyloxy Ynamides or 1-Alkoxycarbonyloxy Allenamides with Arylboronic Acids.

Jian Cao,* Yulong Kong, Yuan Deng, Guoqiao Lai,* Yuming Cui, Ziqiang Hu, Guanhai Wang

Org. Biomol. Chem. 2012, 10, 9556.

6. Synthesis of δ-Carbolines via a Pd-Catalyzed Sequential Reaction from 2-Iodoanilines and N-Tosyl-enynamines.

Jian Cao,* Yongping Xu, Yulong Kong, Yuming Cui, Ziqiang Hu, Guanhai Wang, Yuan Deng, Guoqiao Lai*

Org. Lett. 2012, 14, 38.

7. Synthesis of 2-Azaanthracenes via a Sequential Sonogashira Coupling/Alkynyl Imine-Allenyl Imine Isomerization/Aza-Diels-Alder/Elimination-Aromatization Reaction.

Jian Cao, Xiongfa Yang, Xinlin Hua, Yuan Deng, Guoqiao Lai*

Org. Lett. 2011, 13, 478.

8. Facile Synthesis of Selenium/Sulfur-Substituted 3-Oxa-bicyclo[4.2.0]octa-1(8),5- diene and Tetrahydro-1H-isochromene via Sequential Three-Component Conjugate Addition/Condensation/Elimination/[2+2] or [4+2] Cyclization Reactions.

Jian Cao, Xian Huang, Luling Wu*

J. Org. Chem. 2011, 76, 1440.

9. Facile Synthesis of Tetrahydro-1H-isoindolones via a Sequential Three- Component Copper-Catalyzed Coupling/Propargyl-Allenyl Isomerization/[4+2] Cyclization Reaction.

Jian Cao, Xian Huang*

Org. Lett. 2010, 12, 5048.