蒋可志

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【个人简介】:蒋可志,男,浙江永嘉人,博士,副研究员,硕士生导师,浙江省分析测试协会色谱质谱专业委员会青年委员副主任,《Journal of Separation Science》、《Analytical Method》等分析化学期刊审稿人。现主要从事色谱分析、有机质谱分析、色谱-质谱联用分析,以及有机硅材料分析的研究;在分析化学领域具有较高影响力的国际期刊上发表多篇论文;并主持国家自然科学基金1项,浙江省自然科学基金2项、浙江省分析测试项目1项、浙江省教育厅基金1项校科研启动基金多项。

【电子邮件】:jiangkezhi@hznu.edu.cn; jiangkezhi315@163.com

【主要学历】

1998.09 — 2002.07 学士(工学),浙江工业大学

2002.09 — 2005.03 硕士(理学),浙江大学

2007.09 — 2011.03 博士(理学),浙江大学

【主要学术经历】

2005.03 —  杭州师范大学有机硅实验室,助理研究员,副研究员

【主要研究方向】

l       有机质谱研究(质谱碎裂机理研究、异构体的质谱识别等)

l       色谱分析研究(气相色谱、液相色谱、离子色谱等)

l       有机硅材料分析、有机硅材料在分析化学中应用研究

【主要科研项目及角色】

1. 地表水中新型污染物甲基硅氧烷的痕量检测研究,浙江省分析测试项目(2016C37017,2016/01-2017/12,5.0万元,在研,项目负责人。

2. 浙江省自然科学基金,LY15B050007,芳香胺异构体分析及其水体中多残留检测研究,2015/01-2017/12,8万元,在研,项目负责人。

3.   缩氨硫脲金属络合物的气相离子化学行为与结构表征研究,国家自然科学基金(21205025),25万元,2013.1-2015.12,项目负责人。

4.   结合串联质谱和理论计算研究酰胺氢在气相离子碎裂过程中的作用,浙江省自然科学基金(4100020),5万元,2010.06-2013.06,项目负责人。

5.   苯基硅烷类化合物的质谱行为研究浙江省教育厅科研项目20051896),0.35万,2005.01-2007.12,项目负责人

【近五年来论文发表(第一作者通讯作者)】

1Kezhi Jiang, Gaofeng Bian, Yuanjiang Pan, Guoqiao Lai. Recognizing ortho-, meta- or para- Positional Isomers of S-methyl Methoxylphenylmethylenehydrazine Dithiocarboxylates by ESI-MS2: the Positional Effect of the Methoxyl Substituent Int. J. Mass Spectrom. 2011, 299: 13-19

2Kezhi Jiang, Gaofeng Bian, Yunfeng Chai, Huameng Yang, Quoqiao Lai, Yuanjiang Pan. Electrospray Mass Spectrometric Studies of Nickel(II)- Thiosemicarbazones Complexes: Intra-Complex Proton Transfer in the Gas Phase Ligand Exchange Reactions. Int. J. Mass Spectrom. 2012, 321–322: 40–48.

3Fei Li, Xiaoping Zhang, Huarong Zhang, Kezhi Jiang*. Gas-phase fragmentation of the protonated benzyl ester of proline: intramolecular electrophilic substitution versus hydride transfer. J. Mass Spectrom. 2013, 48, 423–429.

4Xiaoping Zhang, Fei Li, Huiqing Lv, Yanqing Wu, Gaofeng Bian, Kezhi Jiang*. On the origin of the methyl radical loss from deprotonated ferulic and isoferulic acids: electronic excitation of a transient structure. J. Am. Soc. Mass Spectrom. 2013, 24, 941–948.

5Kezhi Jiang, Hu Zhang, Jianmei Wang, Fei Li, Mingrong Qian. Fragmentation of Deprotonated Diacylhydrazine Derivatives in Electrospray Ionization Tandem Mass Spectrometry: Generation of Acid Anions via Intramolecular Rearrangement. Plos One, 2013, 8, e63097. doi:10.1371/journal.pone.0063097

6、李飞,张华蓉,蒋剑雄,蒋可志* 氯硅烷的质谱碎裂规律研究:稳定的Si-Cl.杭州师范大学学报(自然科学版)201312-4297-300

7Huiqing Lv, Xiaoping Zhang, XueZhi Chen, Zhijun Xie, Changfeng Hu, Chengping Wen*, Kezhi Jiang*. Phytochemical Compositions and Antioxidant and Anti-Inflammatory Activities of Crude Extracts fromFicus pandurata H. (Moraceae). Evidence-Based Complementary and Alternative Medicine. 2013, Article ID 215036. http://dx.doi.org/10.1155 /2013/215036

8Yan-Qing Wu, Ning-Wen Zhang, Fei Li, Ke-Zhi Jiang*. Deviant mass shift of hydrated product ions from sodiated β-anilinodidrochalcones using an ion-trap mass spectrometer. Eur. J. Mass Spectrom. 2013,19, 351–359

9. Fei Li, Yanqing Wu, Ningwen Zhang, Jianxiong Jiang*, Kezhi Jiang*. Competing benzyl cation transfers in the gas-phase fragmentation of the protonated benzyl phenylalaninates. Int. J. Mass Spectrom. 2014.369, 23-29

10. Yanqing Wu, Cheng Guo, Ningwen Zhang, Gaofeng Bian, Kezhi Jiang*. Rapid differentiation of ortho-, meta-, and para-isomers of halogenated phenylmethylidene hydrazinecarbodithioates by metal complexation and electrospray ionization mass spectrometry. Rap. Commun. Mass Spectrom. 2014, 28, 2111–2120.

11. 张宁雯,王姗姗,蒋剑雄,张华蓉,蒋可志*. 离子色谱法测定硅氧烷中微量氯离子. 杭州师范大学学报(自然科学版)2014135),7-10

12. 吴艳青, 李美江, 张宁雯, 王姗姗, 蒋可志*. 硅烷偶联剂Si-69中单质硫与化合态硫的液相色谱分析研究.杭州师范大学学报(自然科学版)2014, 13 (6), 575-578.

13. Xiaoping Zhang; Huiqing Lv; Zuguang Li*; Kezhi Jiang*; Maw-Rong Lee. HPLC/ QTOF-MS/MS application to investigate phenolic constituents from Ficus pandurata H. aerial roots. Biomedical Chromatography. 2015, 29, 860-868,

14. Shanshan Wang, Cheng Guo, Ningwen Zhang,Yanqing Wu, Huarong Zhang*, Kezhi Jiang*. Tosyl oxygen transfer and ion–neutral complex mediated electron transfer in the gas-phase fragmentation of the protonated N-phenyl p-toluenesulfonamides. Int. J. Mass Spectrom. 2015, 376, 6-12.

15. Xiaoping Zhang, Peixi Zhu, Huarong Zhang, Zuguang Li*, Kezhi Jiang*, Maw-Rong Lee. The competing radical eliminations in the tandem mass spectrometry of the OH-deprotonated benzyl vanillate. J. Mass Spectrom. 2015, 50, 432-436.

16. Xiaoping Zhang; Kezhi Jiang *; Jingfeng Zou; Zuguang Li*. Two Competing Ionization Processes in Electrospray Mass Spectrometry of Indolyl Benzo[b]carbazoles: Formation of M+• versus [M+H]+. Rap. Commun. Mass Spectrom. 2015,29,263–268.

17. 张宁雯; 王姗姗; 蒋剑雄;蒋可志*. 白炭黑中钠离子和铵离子同时检测及在产品质量控制中应用研究. 杭州师范大学学报(自然科学版)2015141),11-14

18. Xiaoping Zhang; Kezhi Jiang;* Xingfeng Bai; Huiqing Lv; Zuguang Li;* Maw-Rong Lee. Observation of the intermediates of in-source aldolization reactions in electrospray ionization mass spectrometry analysis of heteroaromatic aldehydes. Eur. J. Mass Spectrom. 2015, 21, 51-57. doi: 10.1255/ejms.1307.

19. Kezhi Jiang; Ningwen Zhang; Hu Zhang; Jianmei Wang; Mingrong Qian. Investigation on the Gas-Phase Decomposition of Trichlorfon by GC-MS and Theoretical Calculation. PLoS ONE. 2015, 10(4): e0121389.

20. Shanshan Wang; Lian Yu; Yanqing Wu; Cheng Guo*; Ningwen Zhang; Kezhi Jiang*. Gas-Phase Fragmentation of Protonated N,2-Diphenyl-N'-(p-Toluenesulfonyl)Ethanimidamides: Tosyl Cation Transfer Versus Proton Transfer. J. Am. Soc. Mass Spectrom. 2015, 26, 1428-1431

21. 王姗姗;吴艳青;蒋可志*;张丽君. 锂离子介导的硅烷偶联剂Si69质谱裂解研究. 杭州师范大学学报自然科学版2015144),337-341.

22. 张小平;蒋可志*;吕惠卿;聂晶;李祖光*. HPLC-Q-TOF MS鉴定条叶榕根茎乙酸乙酯提取物中的主要化学成分. 质谱学报. 2015364)310-320.

23. 朱培曦;贾飞;陈悦;陆静娴;潘芳芳;李会林;郑金琪;蒋可志*; . 两对头孢菌素类抗生素异构体的质谱识别研究. 质谱学报,201536(4)350-358

24. Shanshan Wang; Cheng Dong; Lian Yu; Cheng Guo*; Kezhi Jiang*. Dissociation of protonated N-(3-phenyl-2H-chromen-2-ylidene) benzenesulfonamide in the gas phase: cyclization via sulfonyl cation transfer. Rapid Commun. Mass Spectrom. 2016, 30, 95–100.

25. Xiaoping Zhang, Xingfeng Bai, Liwen Fang, Kezhi Jiang,* Zuguang Li*. Decarboxylative Coupling Reaction in ESI()-MS/MS of 4-Nitrobenzyl 4-Hydroxybenzoates: Triplet Ion–Neutral Complex-Mediated 4-Nitrobenzyl Transfer. J. Am. Soc. Mass Spectrom. 2016, 27, 940-943.

26方丽雯,陈萌萌,朱晓清,瞿志荣,蒋可志* 羟基硅油的基质辅助激光解吸电离飞行时间质谱表征研究. 杭州师范大学学报(自然科学版)2016, 15(2), 119-123.